John Harry MacMillan Chemistry Publications and Patents

2. Thomas R.P. Gibb Jr., J.H. MacMillan and R.J. Roy, "The Magnetic Susceptibility of Palladium Hydride", J. Phys. Chem., Vol. 70, p3024 (1966).

FULL PAPER (Google Document)

2a. Thomas R.P. Gibb Jr. and John H. MacMillan, "Magnetic Susceptibility Effects on Removal of Hydrogen from Beta Phase Palladium Hydride", Tufts University, Undergraduate Thesis, 1966.

FULL PAPER (Google Document) COMPLETE THESIS (Google Document)

3. Alfred Viola and John H. MacMillan, "Vapor Phase Thermolysis of 1-Hexen-5-yn-3-ol, An Acetylenic Oxy-Cope Reaction" J. Am. Chem. Soc., Vol. 90, p 6141, (1968).

FULL PAPER (Google Document)

4. Alfred Viola and John H. MacMillan, "A Novel Steric Effect in the Thermolysis of Prop-2-ynyl Vinyl Carbinols" Chemical Communications p 301, (1970).

DOI: 10.1039/C29700000301

FULL PAPER (Google Document)

5. Alfred Viola and John H. MacMillan, "The Vapor Phase Acetylenic Oxy-Cope Reaction of 5-Hexen-1-yn-3-ol , The Chemistry of an Allenol Intermediate", J. Am. Chem. Soc., Vol. 92, p 2404, (1970).

DOI: 10.1021/ja00711a034

FULL PAPER (Google Document)

6. Alfred Viola and John H. MacMillan, "Addition of Grignard Reagents to Allylic and Propargylic Alcohols", J.H. MacMillan, Ph.D. Thesis, Northeastern University, 1970.

FULL PAPER (Google Document)

6a. John H. MacMillan and Alfred Viola,

"Addition of unsaturated propargyl, allyl and benzyl Grignard Reagents to acetylenic or allylic alcohols.", internet archive, 2012.

PDF

FULL PAPER (Google Document)

Internet Archive #2

7. Alfred Viola and John H. MacMillan, " Investigation of Possible Phenyl Participation in the Oxy-Cope and Acetylenic Oxy-Cope Rearrangements" J.H. MacMillan, Ph.D. Thesis, Northeastern University, 1970.

FULL PAPER (Google Document)

8. "Triple Bond Participation in the Oxy-Cope Rearrangement", John H. MacMillan, Ph.D. Thesis, Northeastern University, 1970.

FULL PAPER (Google Document)

PDF (Scanned)

PDF (Retyped)

Internet Archive (retyped)

9. Alfred Viola and John H. MacMillan, "Vapor Phase Thermolysis of 1,5-Hexadiynes, Effect of Hydroxyl Substitution". Presented at the 159th National Meeting of the American Chemical Society Houston Texas, February 1970, Abstract # ORGN 50.

Google Document (Abstract)

FULL PAPER (Google Document)

9a. John H. MacMillan and Alfred Viola "The Acetylenic-Oxy-Cope Rearrangement of 1,5-Hexadiyne-3-ol and Methyl Substituted Derivatives", Internet Archive, 2012.

Google Document PDF

10. Alfred Viola, John H. MacMillan, Robert J. Proverb and Brian L. Yates, "Participation of Acetylenic Bonds in Pericyclic Reactions, Thermal Cleavage of Beta-Hydroxyacetylenes", J. Am. Chem. Soc., Vol. 93, p 6967, (1971).

DOI: 10.1021/ja00754a046

FULL PAPER (Google Document)

11. Alfred Viola, John H. MacMillan, Robert J. Proverb and Brian L. Yates, "Reaction Rates by Flow System Thermolysis, The Competitive Components of the Oxy-Cope Reaction", Chemical Communications, p 936, (1971).

DOI: 10.1039/C29710000936

FULL PAPER(Google Document)

12. John H. MacMillan and Stephen S. Washburne, "Further Studies of the Interaction of Carbonyl Compounds with Organometallic Azides, the Novel Reaction of Benzoquinone with Trimethylsilyl Azide", Report of Investigators to the National Cancer Institute, 1972.

FULL PAPER (Google Document)

13. John H. MacMillan and Stephen S. Washburne "Further Studies of the Interaction of Carbonyl Compounds with Organometallic Azides, the Reaction of Napthoquinones with Trimethylsilyl Azide",

Report of Investigators to the National Cancer Institute, 1972.

FULL PAPER (Google Document)

14. John H. MacMillan and Stephen S. Washburne "Further Studies of the Interaction of Carbonyl Compounds with Organometallic Azides, the Reaction of Acrylonitrile with Trimethylsilyl Azide".

Report of Investigators to the National Cancer Institute, 1973.

FULL PAPER (Google Document)

15. John H. MacMillan and Stephen S. Washburne, "Interaction of Carbonyl Compounds with Organometallic Azides Part V., Sorboyl Chloride and its Conversion to an Alpha-Pyridone", J. Org. Chem., Vol. 38, p 2982, (1973).

DOI: 10.1021/jo00957a013

FULL PAPER (Google Document)

DOI: 10.1002/mrc.1270060414

16. John H. MacMillan and Stephen S. Washburne, "Lanthanide Chemical Shift Reagents as Tools for Determining Isomer Distributions in 2,4-Hexadieneoates and Related Compounds", Organic Magnetic Resonance, Vol. 6, p250, (1974).

FULL PAPER (Google Document)

16a. Supplemental Unpublished Notebook Chemical Shift Data Supporting Paper 16 above.

FULL PAPER (Google Document)

internet archive

CCl.net Archives

17. John H. MacMillan, "Recent Examples of Selectivity in Catalysis", Strem Chemiker, Vol. 11 No. 2, July 1974.

FULL PAPER (Google Document) FULL PAPER (Google Document, in Japanese)

PDF

Internet Archive (in Japanese)

18. John H. MacMillan, Michael E. Strem, Fredrick A. Fowler and George Guy, "An Improved Method for the Preparation of Bis-DiphenylPhosphino Acetylene and unsymmetrical Aryl Substituted Diphenylphosphino Acetylenes", Strem Chemiker, Vol. 11, No. 2, July 1974.

FULL PAPER(Google Document)

19. James D. Warren, John H. MacMillan and Stephen S. Washburne, "Synthesis of Substituted 2H-1,3-Oxazine-2,6-Diones by Reaction of Trimethylsilyl Azide with Maleic Anhydrides", J.Org.Chem., Vol. 40, p 743, (1975).

DOI: 10.1021/jo00894a016

FULL PAPER (Google Document)

DOI: 10.1002/jhet.5570120624

20. John H. MacMillan and Stephen S. Washburne, "Further Investigation of the Interaction of Trimethylsilyl Azide with Substituted Maleic Anhydrides, Synthesis of 4-and 5-Aryl Substituted 1,3(3H) Oxazine-2,6-Diones", J. Heterocyclic Chemistry, Vol. 12, p 1215, (1975).

FULL PAPER (Google Document)

20a. Supplemental Additional 4-and 5-Aryl Substituted 1,3(3H) Oxazine-2,6-Diones

PDF

Google Document (Link2)

21. Mark Lenhart, John H. MacMillan, Alice Maragliano and Steven S. Washburne, "A Facile General Synthesis of Aryl Maleic Anhydrides", Temple University, 1976. Presented at the 10th Middle Atlantic Regional Meeting of the American Chemical Society Philadelphia Pa. February, 1976, Paper 10, Undergraduate research.

FULL PAPER(Google Document)

22. John H. MacMillan and Stephen S. Washburne,^"Hydrolysis reactions of the 4-and 5-Alkyl or Aryl Substituted 1,3(3H) Oxazine-2,6-Diones (Oxauracil) Ring System", Temple University, 1977, Report to the U.S. Army Medical Research and Development command; Grant Number DAMD 17-74-C4100.

FULL PAPER (Google Document)

10.1080/00304947709355668

23. John H. MacMillan, "Improved Procedure for the Preparation of "Oxauracil", 2H-1,3(3H)-Oxazine-2,6-Dione", Organic Preparations and Procedures Int. Vol 9, p 87, (1977).

DOI:

FULL PAPER (Google Document)

10.1080/00268947908069791

24. John H. MacMillan and Mortimer M. Labes, "Low Transition Temperature Liquid Crystalline Amines Incorporating the Trans-1,4-Cyclohexane Ring System", Molecular Crystals and Liquid Crystals, Vol. 55, p 61, (1979).

DOI:

FULL PAPER(Google Document)

PDF

10.1080/01406567908070473

25. John H. MacMillan and Mortimer M. Labes, "Induced Phases in Terminal Mixtures of Polar Liquid Crystalline Amines and Nitriles", Mol. Crystals and Liquid Crystals Letters, Vol. 56, p7, (1979).

DOI:

FULL PAPER (Google Document)

10.1080/01406567908071966

26. John H. MacMillan and Mortimer M. Labes, "Low Transition Temperature Liquid Crystalline Amines Incorporating the Biphenyl Ring System", Mol. Crystals and Liquid Crystals Letters, Vol. 56, p51, (1979).

DOI:

FULL PAPER (Google Document)

27. John H. MacMillan and Mortimer M. Labes, "Synthesis and Photochemistry of Chiral Liquid Crystalline Nitrones", Poster Session, Gordon Research Conference, Liquid Crystals Santa Barbara, California, January, 1980.

POSTER(Google Document) FULL PAPER(Google Document)

FULL PAPER, LINK 2 (Google Document)

28. Eugene R. Bertozzi and John H. MacMillan, "Hexamethylene Glycol Polyformal Copolymers for Insulating Glass and Building Sealants", Thiokol Corporation, Company Private, Sept 15, 1980.

FULL PAPER (Google Document)

29. John H. MacMillan and Mortimer M. Labes, "Amine Substituted Liquid Crystal Compositions", U.S. Patent #4,293,193, Oct. 6, 1981.

Google Document Link

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30. John H. MacMillan, Eugene R. Bertozzi and Bruce E. Streeter, "One Package Heat Curable Sealant Compositions", U.S. Patent #4,430,489, Feb. 7, 1984.

Google Document Link

PDF

European Patent(Google Document) Japanese Patent (Google Document)

Canadian Patent(Google Document)

31. John H. MacMillan, Eugene R. Bertozzi and Bruce E. Streeter, "Thioether Modified Polymer Compositions", U.S. Patent #4,590,240, May 20, 1986.

Google Document Link

Ccl.net Archive

European Patent(Google Document)

32. "Is a Totally Constructivist Approach to the Teaching of High School Chemistry Possible in Practice?", John H. MacMillan Ph.D.

Beaver College, (Arcadia University), 1992.

Internet archive

33. "Virtual Chemistry Laboratory for Non-Science Majors, Good or Bad?", John H. MacMillan Ph.D.

Beaver College, (Arcadia University), 1995.

34. John H. MacMillan, "Using Silanes as Adhesion Promoters", United Chemical Technologies Technical Workshop, 1997, Presented at the 214th Meeting of the American Chemical Society, Los Vegas, Nevada 1997, and the 215th Meeting of the American Chemical Society, Dallas ,Texas , 1998.

35. John H. MacMillan,"Formulating Silicone Adhesives, Rubbers and Gels", United Chemical Technologies Technical Workshop, 1998.

Presented at the 220th National Meeting of the American Chemical Society, Washington, D.C. 2000.

36. John H. MacMillan, "Silane Surface Modifying Reagents", United Chemical Technologies Technical Publication, 1998.

PDF

37. "PS200 Hydrophobic Coating", John H. MacMillan Ph.D. , United Chemical Technologies Technical Brochure, 2000.

PDF

Internet archive

38."A method for derivatizing surfaces with aldehyde groups by employing a new alkoxy aldehydic silane", Coyne, Ann N., Benner, Lauren., MacMillan, John H., Telepchak, Michael J., United Chemical Technologies, technical publication, 2001.

Google Document Google Document (link 2)

39. John H. MacMillan, "Homogeneous Platinum Catalysts", United Chemical Technologies Technical Workshop, Presented at the 222nd Natioinal Meeting of the American Chemical Society, Chicago, Illinois, 2001.

PDF

40. "Platinum Catalysts", John H. MacMillan, Technical Brochure, United Chemical Technologies, 2001.

PDF File

41. Marzinke; Marla, (Ft. Washington, PA); MacMillan; John H., (Ambler, PA); August; Thomas F., (Glenolden, PA); Telepchak; Michael J., (Yardley, PA); "Method for the preparation of aminopropyl or aminoalkyl functional polyalkyl or aryl siloxanes".

United States Patent 6,177,583, January 23, 2001.

Google Document Link

42. Wayne King, John H. MacMillan and Michael J. Telepchak, "Siloxane modified carboxylic acid substituted amines and salts thereof", U.S. Patent 6,489,499, December 3, 2002.

Link Google Document

43. Ann N. Coyne, John H. MacMillan and Michael J. Telepchak, "Supported aldehydic silanes and method of manufacture", U.S. Patent 6,589,799, July 8, 2003.

Link Google Document

44. Ann N. Coyne, John H. MacMillan and Michael J. Telepchak, "Supported aldehydic silanes and method of manufacture", U.S. Patent 7,045,365, May 16, 2006.

Link Google Document

Internet archive

45. John H. MacMillan and Stephen S. Washburne," Oxidative dehydration of aryl substituted succinic acids with selenium dioxide; 4-Bromophenyl maleic anhydride".

DOI: http://dx.doi.org/10.1039/SP525

Chemspider, January 5, 2012

46. John H. MacMillan and Stephen S. Washburne, "Nitrogen insertion reaction of trimethylsilyl azide with aryl substituted maleic anhydrides, yielding aryl substituted 1,3(3H) oxazine-2,6-diones; 4-(4-bromophenyl)-1,3(3H) oxazine-2,6-dione".

DOI: http://dx.doi.org/10.1039/SP526

Chemspider January 16, 2012

47. John H. MacMillan and Stephen S. Washburne, "Oxazine-2,6-dione N-methylation with dimethyl sulfate; N-Methyl-4-(4-methylphenyl)-1,3(3H)-oxazine-2,6-dione".

DOI: http://dx.doi.org/10.1039/SP529

Chemspider January 16, 2012

48. John H. MacMillan and Alfred Viola, " Preparation of acetylenic alcohols by addition of propargyl Grignard reagents activated at low temperatures with mercury ion to a,ß-unsaturated aldehydes and ketones", Internet Archive, 2012.

PDF Google Doc

49. John H. MacMillan and Alfred Viola, "Addition of propargyl Grignard to aldehyde; 1-Phenyl-3-butyne-1-ol".

DOI: http://dx.doi.org/10.1039/SP537

Chemspider February 17, 2012

50. John H. MacMillan and Alfred Viola, "Addition of Allyl Magnesium Chloride to Propynal, 5-Hexen-1-yn-3-ol”.

DOI: http://dx.doi.org/10.1039/SP579